As part of what we planned to accomplish, we looked up on a key ingredient to our venture and that is Chocolate and we found some really great stuff written about Chocolate over at Wikipedia.
Below is the excerpt from Wikipedia relating to Chocolate & Chocolate Dipped:
Chocolate comprises a number of raw and processed foods that are produced from the seed of the tropical cacao tree. Native to lowland tropical South America, cacao has been cultivated for three millennia in Central America and Mexico, with its earliest documented use around 1100 BC. All of the Mesoamerican peoples made chocolate beverages, including the Maya and Aztecs, who made it into a beverage known as xocolātl, a Nahuatl word meaning “bitter water”. The seeds of the cacao tree have an intense bitter taste, and must be fermented to develop the flavor. After being roasted and ground, the resulting products are known as chocolate or cocoa.
Much of the chocolate consumed today is made into bars that combine cocoa solids, fats like cocoa butter, and sugar. Chocolate has become one of the most popular flavours in the world. Gifts of foiled wrapped chocolate molded into different shapes has become traditional on certain holidays: chocolate bunnies and eggs are popular on Easter, coins on Hanukkah, Santa Claus and other holiday symbols on Christmas, and hearts on Valentine’s Day. Chocolate is also used in cold and hot beverages, to produce chocolate milk and cocoa.
Chocolate contains alkaloids such as theobromine and phenethylamine, which have physiological effects on the body. It has been linked to serotonin levels in the brain. Scientists claim that chocolate, eaten in moderation, can lower blood pressure. The presence of theobromine renders it toxic to some animals.
History
The word “chocolate” comes from the Aztecs of Mexico, and is derived from the Nahuatl word xocolatl (IPA /ʃo’kola:tɬ/), which is a combination of the words, xocolli, meaning “bitter”, and atl, which is “water”. The Aztecs associated chocolate with Xochiquetzal, the goddess of fertility. Chocolate is also associated with the Mayan god of fertility. Mexican philologist Ignacio Davila Garibi, proposed that “Spaniards had coined the word by taking the Maya word chocol and then replacing the Maya term for water, haa, with the Aztec one, atl.” However, it is more likely that the Aztecs themselves coined the term, having long adopted into Nahuatl the Mayan word for the “cacao” bean; the Spanish had little contact with the Mayans before Cortés’s early reports to the Spanish King of the beverage known as xocolatl. However, Micheal D. Coe, professor Emeritus of Anthropology and Curator Emeritus in the Peabody Museum of Natural History at Yale University, and coauthor of the book The True History of Chocolate, argues that the word xocolatl appears in “no truly early source on the Nahuatl language or on Aztec culture.”
Chocolate has been used solely as a drink for nearly all of its history. The earliest record of using chocolate pre-dates the Mayans. Chocolate residue has been found in pottery dating to 1100 BC from Honduras, and 600-400 BC from Belize. The chocolate residue found in an early classic ancient Maya pot in Río Azul, northern Guatemala, suggests that Mayans were drinking chocolate around 400 A.D.. In the New World, chocolate was consumed in a bitter, spicy drink called xocoatl, and was often flavored with vanilla, chile pepper, and achiote (known today as annatto). Xocoatl was believed to fight fatigue, a belief that is probably attributable to the theobromine content. Other chocolate drinks combined it with such edibles as maize starch paste (which acts as an emulsifier and thickener), various fruits, and honey. In 1689 noted physician and collector Hans Sloane, developed a milk chocolate drink in Jamaica which was initially used by apothecaries, but later sold by the Cadbury brothers.
Chocolate was also an important luxury good throughout pre-Columbian Mesoamerica, and cacao beans were often used as currency. For example, the Aztecs used a system in which one turkey cost one hundred cacao beans and one avocado was worth three beans.
Production
Roughly two-thirds of the entire world’s cocoa is produced in Western Africa, with close to half of the total sourced from Côte d’Ivoire. Like many food industry producers, individual cocoa farmers are at the mercy of volatile world markets. The price can vary from £500 ($945) to £3,000 ($5,672) per ton, in the space of just a few years. While investors trading in cacao can dump shares at will, individual cocoa farmers cannot increase production or abandon trees at anywhere near that pace. When cocoa prices drop, farmers in West Africa sometimes cut costs by using slave labor. It has been alleged that an estimated 90% of cocoa farms in Côte d’Ivoire have used some form of slave labor in order to remain viable. According to the World Cocoa Foundaton, some 50 million people around the world depend on cocoa as a source of livelihood.
Despite some disagreement in the EU about the definition, chocolate is any product made primarily of cocoa solids and cocoa fat. The different flavours of chocolate can be obtained by varying the time and temperature when roasting the beans, by adjusting the relative quantities of the cocoa solids and cocoa fat, and by adding non-chocolate ingredients.
Production costs can be decreased by reducing cocoa solid content or by substituting cocoa butter with a non-cocoa fat, but allowing chocolate to be made with vegetable oils could have serious consequences for the millions of growers whose livelihoods depend on cocoa.
There are two main jobs associated with creating chocolate candy, chocolate makers and chocolatiers. Chocolate makers use harvested cacao beans and other ingredients to produce couverture chocolate. Chocolatiers use the finished couverture to make chocolate candies (bars, truffles, baked goods, etc.).
Bean
The three main varieties of cacao beans used in chocolate are Criollo, Forastero and Trinitario.
Criollo is the rarest and most expensive cocoa on the market and is native to Central America, the Caribbean islands and the northern tier of South American states. There is some dispute about the genetic purity of cocoas sold today as Criollo, because most populations have been exposed to the genetic influence of other varieties. Criollos are particularly difficult to grow, as they are vulnerable to a variety of environmental threats and produce low yields of cocoa per tree. The flavour of Criollo is unique. It is described as delicate yet complex, low in classic chocolate flavour, but rich in “secondary” notes of long duration.
Forastero is a large group of wild and cultivated cacaos, most likely native to the Amazon basin. The African cocoa crop is entirely of the Forastero variety. They are significantly hardier and of higher yield than Criollo. Forastero cocoas are typically strong in classic “chocolate” flavour, but have a short duration and are unsupported by secondary flavours. There are exceptional Forasteros, such as the “Nacional” or the “Arriba” varieties, which can be very complex flavors.
Trinitario is a natural hybrid of Criollo and Forastero. Trinitario originated in Trinidad (hence the name) after an introduction of (Amelonado) Forastero to the local Criollo crop. These cocoas encompass a wide range of flavour profiles according to the genetic heritage of each tree.
Nearly all cacao produced over the past five decades is of the Forastero or lower-grade Trinitario varieties. The share of higher quality Criollos and Trinitarios (so-called flavour cacao) is just under 5% per annum.
Cacao trees are difficult to grow and cultivate as they will only grow twenty degrees north and twenty degrees south of the equator. The temperature for cacao trees cannot drop below sixty degrees Fahrenheit without damaging the tree.
Harvesting
Harvesting cacao beans is a delicate process. First, the pods, containing cacao beans, are harvested. The beans, together with their surrounding pulp, are removed from the pod and placed in piles or bins to ferment for three to seven days. The fermentation process is what gives the beans their familiar chocolate taste. The beans must then be quickly dried to prevent mold growth; weather permitting, this is done by spreading the beans out in the sun.
Chocolate liquor
The dried beans are transported from the plantation where they were grown to a chocolate manufacturing facility.
The beans are then cleaned (removing twigs, stones, and other debris), roasted, and graded. Next the shells are removed to extract the nib. Finally, the nibs are ground which releases and melts the cocoa butter producing chocolate liquor.
There are three things that can be done with the chocolate liquor at this point:
- It can be solidified and sold as unsweetened baking chocolate.
- Cocoa butter can be removed from it and the result is cocoa powder. There are several mechanisms for removing cocoa butter from chocolate liquor. These include using hydraulic pressure and the Broma process.
- Cocoa butter can be added to it to make eating chocolate.
Blending
Chocolate liquor is blended with the cocoa butter in varying quantities to make different types of chocolate or couvertures. The basic blends of ingredients for the various types of chocolate (in order of highest quantity of cocoa liquor first), are as follows:
- Dark chocolate: sugar, cocoa butter, cocoa liquor, and (sometimes) vanilla
- Milk chocolate: sugar, cocoa butter, cocoa liquor, milk or milk powder, and vanilla
- White chocolate: sugar, cocoa butter, milk or milk powder, and vanilla
Usually, an emulsifying agent such as soya lecithin is added, though a few manufacturers prefer to exclude this ingredient for purity reasons and to remain GMO-free (Soya is a heavily genetically modified crop), sometimes at the cost of a perfectly smooth texture. Some manufacturers are now using PGPR, an artificial emulsifier derived from castor oil that allows them to reduce the amount of cocoa butter while maintaining the same mouthfeel.
The texture is also heavily influenced by processing, specifically conching (see below). The more expensive chocolates tend to be processed longer and thus have a smoother texture and “feel” on the tongue, regardless of whether emulsifying agents are added.
Different manufacturers develop their own “signature” blends based on the above formulas but varying proportions of the different constituents are used.
The finest plain dark chocolate couvertures contain at least 70% cocoa (solids + butter), whereas milk chocolate usually contains up to 50%. High-quality white chocolate couvertures contain only about 33% cocoa. Some mass-produced chocolate contains much less cocoa (as low as 7% in many cases) and fats other than cocoa butter. Some chocolate makers say that these “chocolate” products should not be classed as couvertures, or even as chocolate, because of the low or virtually non-existent cocoa content.
In 2007, the Chocolate Manufacturers Association in the United States, whose members include Hershey, Nestlé, and Archer Daniels Midland, lobbied the Food and Drug Administration to change the legal definition of chocolate to let them substitute partially hydrogenated vegetable oils for cocoa butter in addition to using artificial sweeteners and milk substitutes. Currently, the FDA does not allow a product to be referred to as “chocolate” if the product contains any of these ingredients.
Conching
The penultimate process is called conching. A conche is a container filled with metal beads, which act as grinders. The refined and blended chocolate mass is kept liquid by frictional heat. The conching process produces cocoa and sugar particles smaller than the tongue can detect, hence the smooth feel in the mouth. The length of the conching process determines the final smoothness and quality of the chocolate. High-quality chocolate is conched for about 72 hours, lesser grades about four to six hours. After the process is complete, the chocolate mass is stored in tanks heated to approximately 45–50 °C (113–122 °F) until final processing.
Tempering
The final process is called tempering. Uncontrolled crystallization of cocoa butter typically results in crystals of varying size, some or all large enough to be clearly seen with the naked eye. This causes the surface of the chocolate to appear mottled and matte, and causes the chocolate to crumble rather than snap when broken. The uniform sheen and crisp bite of properly processed chocolate are the result of consistently small cocoa butter crystals produced by the tempering process.
The fats in cocoa butter can crystallize in six different forms (polymorphous crystallization). The primary purpose of tempering is to assure that only the best form is present. The six different crystal forms have different properties.
| Crystal |
Melting Temp. |
Notes |
| I |
17 °C (63 °F) |
Soft, crumbly, melts too easily. |
| II |
21 °C (70 °F) |
Soft, crumbly, melts too easily. |
| III |
26 °C (78 °F) |
Firm, poor snap, melts too easily. |
| IV |
28 °C (82 °F) |
Firm, good snap, melts too easily. |
| V |
34 °C (94 °F) |
Glossy, firm, best snap, melts near body temperature (37 °C). |
| VI |
36 °C (97 °F) |
Hard, takes weeks to form. |
Making good chocolate is about forming the most of the type V crystals. This provides the best appearance and mouth feel and creates the most stable crystals so the texture and appearance will not degrade over time. To accomplish this, the temperature is carefully manipulated during the crystallization.
Generally, the chocolate is first heated to 45 °C (113 °F) to melt all six forms of crystals. Then the chocolate is cooled to about 27 °C (80 °F), which will allow crystal types IV and V to form (VI takes too long to form). At this temperature, the chocolate is agitated to create many small crystal “seeds” which will serve as nuclei to create small crystals in the chocolate. The chocolate is then heated to about 31 °C (88 °F) to eliminate any type IV crystals, leaving just the type V. After this point, any excessive heating of the chocolate will destroy the temper and this process will have to be repeated. However, there are other methods of chocolate tempering used– the most common variant is introducing already tempered, solid “seed” chocolate. The temper of chocolate can be measured with a chocolate temper meter to ensure accuracy and consistency. A sample cup is filled with the chocolate and placed in the unit which then displays or prints the results.
Two classic ways of manually tempering chocolate are:
- Working the molten chocolate on a heat-absorbing surface, such as a stone slab, until thickening indicates the presence of sufficient crystal “seeds”; the chocolate is then gently warmed to working temperature.
- Stirring solid chocolate into molten chocolate to “inoculate” the liquid chocolate with crystals (this method uses the already formed crystal of the solid chocolate to “seed” the molten chocolate).
Chocolate tempering machines (or temperers) with computer controls can be used for producing consistently tempered chocolate, particularly for large volume applications.
Storing
Chocolate is very sensitive to temperature and humidity. Ideal storage temperatures are between 15 and 17 degrees Celsius (59 to 63 degrees Fahrenheit), with a relative humidity of less than 50%. Chocolate should be stored away from other foods as it can absorb different aromas. Ideally, chocolates are packed or wrapped, and placed in proper storage with the correct humidity and temperature. Additionally chocolate should be stored in a dark place or protected from light by wrapping paper. Various types of “blooming” effects can occur if chocolate is stored or served improperly. If refrigerated or frozen without containment, chocolate can absorb enough moisture to cause a whitish discoloration, the result of fat or sugar crystals rising to the surface. Moving chocolate from one temperature extreme to another, such as from a refrigerator on a hot day can result in an oily texture. Although visually unappealing, these conditions are perfectly safe for consumption.
For more information on Chocolates, please refer to the main article link above.
